Zircon
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What is zircon?
Where is it found?
Important characteristics
Treatments
Radioactivity in gems |
Zircon
Zircon is a zirconium silicate mineral. It is the principle source
of the element zirconium (Zr)
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See a
movie of the zircon structure! |
Where is it formed and where is it found?
The mineral forms square prismatic crystals and grains in igneous and
metamorphic
rocks (large
crystals are rarer)
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usually small and inclusion-rich
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Zircon is highly resistant to weathering (maybe the most resistant of any
mineral) This, and its high specific gravity, favor its concentration in
placer deposits and alluvial gem gravels.
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Gemstones have historically been recovered from many
localities
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Important characteristics:
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Easy to chip
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Doubly refractive with very
obvious doubling of facets. A second example showing doubling
of facets. High dispersion.
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Contains Uranium (U) and thorium (Th)
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undergoes radioactive
decay and leads to damaged crysals ("Metamict") (appear cloudy)
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decay of U and Th occur at specific and well known rates. Measurement of
isotopic abundances allows age dating of zircons ! (Thus zircons are very
important minerals in the geological scheme of things.)
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Treatments:
Metamict crystals + heat (1450 C) can restore crystallinity
Brown
zircon + 800 - 1000 C in reducing environment -> colorless
or blue zircon
Brown zircon + 800 - 1000 C in air-> colorless or golden yellow zircon
Most colorless or blue crystals have been irradiated or heat treated!
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colorless : brilliant cut (colored stones often in emerald cut) to resemble
diamond: you can distinguished by double refraction (which doubles the
image of the facets), and by signs of wear
Note: UV (sunlight) can modify the color!
Heat treatment makes zircons more brittle, facets tend to abrade more
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Radioactivity in Minerals
Detection: Geiger counter
Measurement: many scales:
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nCi = nanoCurie (billionth of a Curie)
Curie is the radioactivity of 1 g of radium
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mrem (thousanth of a rem)
rem = roentgen equivalent man (like a sunburn measure)
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rad = measure of absorbed dose: quantity of radiation able to deposit 100
ergs of energy)
Average
dose the average American receives in one year
360 mrem / year or 1 mrem/day
Safety limit: 5,000 mrem to entire body per year
Gems: calculations are complex, but roughly:
Sc 46 or Ta 182 in blue topaz: ~ 25 nCi/g
Thus: for two identically sized stones:
blue topaz (~ 25 nCi/g)
natural zircon (1.0 nCi/g of U238)
over 10 years dose is exactly the same
Does this matter?
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the average human contains 200 nCi of K40 and eats and drinks ~ 140 nCi
of K40 / year
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the 2 nCi/ g from gems is insignificant.
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