Crystal Systems

GROUP 1GROUP 2SYSTEM
IsotropicCubic
AnisotropicUniaxial(2RIs)Hexagonal
Tetragonal
Biaxial(3RIs)Orthorhombic
Monoclinic
Triclinic

Note: Rhombohedral is a sub-category of hexagonal.

Note: 'Group' refers to type of optical properites. First observe:

If the crystal is uniaxial it belongs to the tetragonal or hexagonal crystal systems, if it is biaxial it belongs to the orthorhombic, monoclinic, or triclinic crystal systems.

Shapes of unit cells are determined by the crystal system, with the following results:

CRYSTAL SYSTEM AXES LENGTHSAXIAL ANGLES
CUBICAll equalAll 90
TETRAGONALa=b not = call 90
HEXAGONALtwo are equal2 are 90, one 120
ORTHORHOMBICall unequalall are 90
MONOCLINICall unequaltwo are 90
TRICLINICall unequalnone are 90
These are the detailed shapes associated with these crystal systems!

Example showing how optical properties that provide information about the crystal system can help distinguish similar looking gems!:

Blue sapphire - hexagonal - thus uniaxial.

Blue colored cubic zirconia (looks like sapphire) - cubic thus isotropic

Tanzanite (blue like sapphire) - orthorhombic thus biaxial.